Preparation and Properties of Poly（ether ether ketone）/Carbon Nanotube Modified Polypropylene Janus Composite Separator北大核心CSCD

Lithium-ion batteries （LIBs）have attracted wide attention because of their broad prospects in electric vehicles. However,the safety problems and low multiplier performance of the commercial polyolefin separator limit their further development,due to the poor dimensional thermal stability and low electrolyte absorption rate. Poly（ether ether ketone）（PEEK）and carbon nanotube（CNT）are compounded to coat on polypropylene （PP） to prepare Janus composite separator （PP@C） through the phase inversion method. PP@C composite separator does not deform at 180 ℃ for 0. 5 h（only slight deformation）,illustrating excellent thermal stability. The electrolyte absorption rate of PP@C2 is 193. 8%. The electrolyte uptake rate of the PP@C2 composite membrane was 193. 8%,which was 64. 5% higher than the PP membrane,showing a superduper electrolyte permeability. As a result,the specific discharge capacity of LIBs assembled with PP@C2 composite separator is 157. 6 mA·h/g at 0. 2 C and 129. 8 mA·h/g at 2 C,showing good rate performance with the capacity recovery rate of more than 99%. This might be attributed to the ultra-high thermal stability of PEEK,the good affinity of the electrolyte,the high conductivity of CNT,as well as the uniform dispersion of Li+ ,so that the separator can have excellent electrochemical performance while improving safety. © 2022, Science Press (China). All rights reserved.     

小波基方法在波传问题中的应用

基于多尺度分析理论，引入哈密顿体系和插值小波变换，分别构造了适合于求解复杂域波传问题的快速自适应方法——多尺度辛格式和插值小波配点格式，利用小波基的局部性与消失矩等特性改善计算效率，并将插值小波应用到波动方程的多尺度反演问题中。讨论了其优缺点并提出几点展望。     

部分输入未知条件下结构动力复合反演的分解算法

在充分利用部分输入已确知而部分输入未知的激励特性的基础上，提出了结构动力复合反演的分解算法，该算法从源头上消除了迭代过程中参数识别与荷载反演的相互影响，降低了问题的计算规模。对于线性参数系统，该算法不经过任何迭代计算即可一次性完成结构参数识别及荷载反演。将其与松弛法结合，可解决非线性参数系统的识别问题，与文献[4]的方法比较，其收敛速度有显著提高。     

Influence of gas injection on phase inversion in an oil–water flow through a vertical tube

An experimental study has been made of the influence of gas injection on the phase inversion between oil and water flowing through a vertical tube. Particular attention was paid to the influence on the critical concentration of oil and water where phase inversion occurs and on the pressure drop increase over the tube during phase inversion. By using different types of gas injectors also the influence of the bubble size of the injected gas on the phase inversion was studied. It was found that gas injection does not significantly change the critical concentration, but the influence on the pressure drop is considerable. For mixture velocities larger than 1 m/s, the pressure drop over the tube increases with decreasing bubble size and at inversion can become even larger than the pressure drop during the flow of oil and water without gas injection.     

用同伦方法反演非饱和土中溶质迁移参数

非饱和土中溶质迁移参数反演问题可以归结为非线性算子方程的求解问题. 将同伦方法 引入该问题的求解，通过构造线性同伦将原问题转化为求解同伦函数最小值的无约束优化问 题. 同时在分析了同伦参数正则化效应的基础上，提出一种两段同伦参数修正方法. 即在求 解的初始阶段，根据拟Sigmoid函数调整同伦参数，以追踪同伦路径，保证计算稳定地进行； 在迭代的后期，采用与残差相关的同伦参数修正方法，以抵抗观测噪声对求解的影响. 数值 算例为求解带有平衡及非平衡吸附效应的一维非饱和土中溶质迁移模型参数反演问题，计算 结果表明了该方法的大范围收敛性及较强的抵抗观测噪声的能力.     

双相介质参数反演的混沌搜索方法

混沌运动能在一定的范围内按自身的规律不重复地遍历所有状态。利用这个特点 ,本文将混沌运动引入到双相介质参数反问题的研究中。首先利用边界元方法实现了由介质参数到地表位移的非线性映射 ,然后通过建立合成位移与实测位移的相关函数将参数识别问题归结为优化问题 ,最后利用混沌运动指导优化搜索求得介质参数。算例结果表明了混沌搜索方法用于双相介质参数反演问题的可行性和有效性     

Aspect ratio effect on natural convection in water near its density maximum temperature

The effect of the aspect ratio on natural convection in water subjected to density inversion has been investigated in this study. Numerical simulations of the two-dimensional, steady state, incompressible flow in a rectangular enclosure with a variety of aspect ratios, ranging from 0.125 to 100, have been accomplished using a finite element model. Computations cover Rayleigh numbers from 10³ to 10⁶. Results reveal that the aspect ratio, A, the Rayleigh number, Ra, and the density distribution parameter, R, are the key parameters to determine the heat transfer and fluid flow characteristics for density inversion fluids in an enclosure. A new correlation for predicting the maximum mean Nusselt number is proposed in the form of , with the constants a and b depending on density distribution number R. It is demonstrated that the aspect ratio has a strong impact on flow patterns and temperature distributions in rectangular enclosures. The stream function ratio Ψ_inv/|Ψ_reg| is introduced to describe quantitatively the interaction between inversional and regular convection. For R=0.33, the density inversion enhancement is observed in the regime near A=3.     

二维介质参数的大扰动反演方法

对非均匀介质参数反演问题进行了研究，并提出了用于反演二维介质参数的广义射线近似方法．利用参考场量和扰动变量对声波方程中的介质参数进行处理，并利用Ｇｒｅｅｎ函数理论得到扰动参数比的积分方程．基于非均匀介质中波函数的局部理论和射线理论，引入了全波场的广义射线近似形式，通过定义介质参数函数，把反演目标归结为其第一类Ｆｒｅｄｈｏｌｍ积分方程．利用积分变换方法得到二维介质的介质参数函数，从而得到介质参数，在Ｂｏｒｎ近似方法中，反演的介质参数扰动不能超过２０％，但是在本文中介绍的方法能够有效地反演其扰动比不超过５０％的变化情况     

弹性动力学反问题的发展和展望

本文介绍了弹性动力学反问题的理论和方法及其在工程实际中的应用。对本学科的当前发展，重点介绍了Ｂｏｒｎ近似的线性化方法和利用弹性波的层析成象技术的理论基础，同时对一些实验技术作了简要介绍。对本学科的进一步发展值得注意解决的问题作了展望。     

Temperature Effect on the Phase Behavior of the Systems Water/Sucrose Laurate/Ethoxylated‐mono‐di‐glyceride/Oil

The phase behavior of the systems water/sucrose laurate/ethoxylated mono‐di‐glyceride/oil was investigated as function of temperature and the weight ratio of EMDG in the mixed surfactants. The oils were R (+)‐limonene, isopropylmyristate, and caprylic‐capric triglyceride. This study demonstrates that the phase inversion temperature (PIT) decreases and the efficiency of the mixed surfactants (γ¯) increase as the weight ratio of the EMDG in the mixed surfactants increases. R (+)‐limonene gave lower phase inversion temperatures and higher efficiencies compared to isopropylmyristate, and caprylic‐capric triglyceride. The solubilization capacity of the system water/sucrose laurate/oil increased upon the addition of ethoxylated mono‐di‐ glyceride which stabilize the surfactant layer and increase the interfacial area.